DMS oxidation
نویسندگان
چکیده
Model study of multiphase DMS oxidation with a focus on halogens R. von Glasow and P. J. Crutzen Center for Atmospheric Sciences, Scripps Institution of Oceanography, University of California, San Diego, La Jolla, CA, 92093-0221, USA Atmospheric Chemistry Division, Max-Planck-Institut für Chemie, PO Box 3060, 55020 Mainz, Germany Received: 26 October 2003 – Accepted: 12 December 2003 – Published: 18 December 2003 Correspondence to: R. von Glasow ([email protected])
منابع مشابه
Photochemical oxidation of dimethylsulphide to dimethylsulphoxide in estuarine and coastal waters.
Dimethylsulphide (DMS) photo-oxidation and dimethylsulphoxide (DMSO) photoproduction were estimated in 26 laboratory irradiations of coastal samples from NE England (Tyne estuary) and W Scotland (Loch Linnhe and River Nant at Taynuilt). Pseudo-first order rate constants of DMS photo-oxidation (0.038 h-1 to 0.345 h-1) and DMSO photo-production (0.017 h-1 to 0.283 h-1) varied by one order of magn...
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We studied the oxidation of dimethylsulfide (DMS) in the marine boundary layer (MBL) with a onedimensional numerical model and focused on the influence of halogens. Our model runs show that there is still significant uncertainty about the end products of the DMS addition pathway, which is especially caused by uncertainty in the product yield of the reaction of the intermediate product methyl su...
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